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Carbon dioxide chemical formula9/18/2023 ![]() ![]() Many metal-CO complexes are prepared by decarbonylation of organic solvents, not from CO. One of the most important metal carbonyls is iron pentacarbonyl, Fe(CO) 5: In these situations, carbon monoxide is called the carbonyl ligand. In nickel carbonyl and other carbonyls, the electron pair on the carbon interacts with the metal the carbon monoxide donates the electron pair to the metal. Nickel carbonyl decomposes readily back to Ni and CO upon contact with hot surfaces, and this method was once used for the industrial purification of nickel in the Mond process. For this reason, nickel in any tubing or part must not come into prolonged contact with carbon monoxide (corrosion). In nickel carbonyl, Ni(CO) 4 forms by the direct combination of carbon monoxide and nickel metal at room temperature. The lone pair on the carbon atom in CO, also donates electron density to the d x²−y² on the metal to form a sigma bond. This is because there must be sufficient electron density to facilitate back donation from the metal d xz-orbital, to the π* molecular orbital from CO. Only those in lower oxidation states will complex with carbon monoxide ligands. Most metals form coordination complexes containing covalently attached carbon monoxide. This process is responsible for most of the industrial production of acetic acid.Ĭarbon monoxide is a principle component of syngas, which is often used for industrial power.Ĭarbon monoxide(CO) is also used in industrial scale operations for purify Nickel, it is a precursor for an corrosion process called Mond Process. In the Monsanto process, carbon monoxide and methanol react in the presence of a homogeneous rhodium catalyst and HI to give acetic acid. This technology allows coal to be converted to petrol. In a related reaction, the hydrogenation of CO is coupled to C-C bond formation, as in the Fischer-Tropsch process where CO is hydrogenated to liquid hydrocarbon fuels. Methanol is produced by the hydrogenation of CO. In one of many applications of this technology, hydroformylation is coupled to the Shell Higher Olefin Process to give precursors to detergents. ![]() High volume aldehydes are produced by the hydroformylation reaction of alkenes, CO, and H 2. Principal chemical reactions Industrial usesĬarbon monoxide is a major industrial gas that has many applications in bulk chemicals manufacturing. The physical properties of N 2 and CO are similar, although CO is more reactive. This is illustrated by the reactivity of carbon monoxide: it reacts with carbocations.ĭinitrogen is isoelectronic to carbon monoxide, which means that these molecules have the same number of electrons and similar bonding. The leftmost resonance form is the most important. The molecule has a small dipole moment and can be represented by three resonance structures: The molecule's bond length is consistent with a partial triple bond. This is also the reason that almost all chemistry involving carbon monoxide occurs through the carbon atom, and not the oxygen. In addition, carbon's lower electronegativity creates a much more diffuse electron cloud, enhancing the dipole moment. The reason for this, despite oxygen's greater electronegativity, is that the highest occupied molecular orbital has an energy much closer to that of carbon's p orbitals, meaning that greater electron density is found near the carbon. The result is a small dipole moment with its negative end on the carbon atom. Formal charge and electronegativity difference cancel each other out. ![]() The CO molecule is characterized by a bond length of 0.1128 nm. Another laboratory preparation for carbon monoxide entails heating an intimate mixture of powdered zinc metal and calcium carbonate.Īnother lab style of generate CO is reacting Sucrose and Sodium Hydroxide in a closed system. As such it is conveniently produced by the dehydration of formic acid, for example with sulfuric acid. The Ellingham diagram shows that CO formation is favored over CO 2 in high temperatures.ĬO is the anhydride of formic acid. Since CO is a gas, the reduction process can be driven by heating, exploiting the positive (favorable) entropy of reaction. Synthesis gas or Water gas is produced via the endothermic reaction of steam and carbon:ĬO also is a byproduct of the reduction of metal oxide ores with carbon, shown in a simplified form as follows: The downside of this method is if done with air it leaves a mixture that is mostly nitrogen. Above 800 ☌, CO is the predominant product: The reaction of O 2 with carbon to give CO is described as the Boudouard equilibrium. The initially produced CO 2 equilibrates with the remaining hot carbon to give CO. In an oven, air is passed through a bed of coke. Producer gas is formed by combustion of carbon in oxygen at high temperatures when there is an excess of carbon. Carbon monoxide is so fundamentally important that many methods have been developed for its production. ![]()
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Black green lantern pop9/18/2023 ![]() ![]() After realizing that the "Blackest Night" prophecy will come to pass, Ganthet and Sayd depart after creating a Blue Lantern Ring with the intention of creating their own Corps. In the aftermath of the war, the Guardians decide to bring the second of the new laws into effect. Ganthet also reveals that in the coming future, each color will have its own forces like the Lantern Corps, and these forces will fight against the others in a War of Light across the universe that will lead into the event known as "The Blackest Night", the worst of the hidden prophecies of the Book of Oa. The further towards one end of the spectrum an energy color is, the more diffiuclt its power is to control, leading to a corruptive influence over the user. ![]() Ganthet and Sayd also explain to the four about the Emotional Spectrum created at the start of sentience that is separated into 7 colors: green (willpower), yellow (fear), violet (love), red (hate), indigo (compassion), orange (greed), and blue (hope), each representing different forms of emotion, with green being in the center and balancing the energies. The four men then take their lanterns and hearing the Sinestro Corps oath, recite the classic Green Lantern oath, and depart to confront the Sinestro Corps. He asks if Kyle is willing to downgrade himself to a normal Green Lantern, which Kyle quickly agrees too. Ganthet's final act as Guardian is to make Kyle a new power ring. As Ganthet explains, he and Sayd were kicked out of the Guardians of the Universe. Just as Parallax (now back in his monster form) attacks the Lanterns for freeing Kyle Rayner, Ganthet and Sayd arrive and draw Parallax into four separate lanterns ( Hal, Kyle, John, and Guy's, respectively). He also acknowledged, however, that even the Guardians themselves did not know exactly what the Blackest Night was.ĭuring the Sinestro Corps War, Ganthet and a female Guardian named Sayd are banished from the council for feeling emotion. Ganthet called the Sinestro Corps invasion of Earth the second verse of the hidden chapter, with the Blackest Night itself being the third and final verse. Ībin Sur initially uncovered this prophecy and was forbidden to speak of it. ![]() The Guardians refer to this prophecy as the last and hidden chapter of the Book, describing their final fate and ultimate purpose because they did the forbidden - they felt fear. And a wave of light will unleash the truth behind the power of the ring. The Book of Oa, a sacred text of the Guardians of the Universe, contains a prophecy called "The Blackest Night", which states:Ī face of metal and flesh shall speak of the secrets of the 52. 1.13 The Sentient Embodiment of Life Revealed. ![]()
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Best waterfall drinking game rules9/17/2023 ![]() Common rules include something everyone must do or say if “this” happens or is said. – The spinner may make a new rule that causes someone to drink. The Question Master may ask anyone a question at any time, and if they do not ask another question back or stay silent, they must drink. – The spinner is now the Question Master until the next Question Master is chosen. If someone says they haven’t done something, but someone else successfully challenges it, the challenged must drink. The first person or people to put down all their fingers must drink. Starting with the spinner, the circle states something they have never done. The circle must say something falling under the category. Whoever hesitates or repeats something that has already been said, must drink. Whoever hesitates or repeats a word or phrase already been said, must drink. The circle must rhyme with the word or phrase. The last person to put their thumb on the table drinks. Everyone must put their thumb on the table. ![]() At any one time during the game, the Thumb Master may discreetly put their thumb on the table. Last person to put both of their hands in the air, must drink. Whoever hesitates, says the wrong thing, or says something when they shouldn’t, must drink. – The spinner starts the count off with “1.” The next player continues the count around the circle, but any number that is a multiple of 7 or containing a 7 digit must be replaced with “Fat Boy.” Once “Fat Boy” is said, the direction of the count is reversed. ![]() The pair lasts until another Date/Mate is chosen. This pair must drink together any time one or the other must drink. ![]() – The spinner chooses another partner to drink with. Everyone takes turns spinning the wheel and following instructions. This drinking game is based off the card game known as “Kings,” “Circle of Death,” and other names as well. ![]()
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Time out west sports bar9/17/2023 ![]() ![]() ![]() Episodes are shot in real-time for 5-day stretches, however, considerable planning happens ahead of time.Ģ47 episodes, including 1 removed episode ( unintentionally aired), have aired as of May 28, 2023. Time Out West Sports Pub, Hanover Park, Illinois. Time Out West Sports Pub, Hanover Park, Illinois. Throughout the show's history, multiple bars have restored their original name or motif after filming wraps. Additionally, the businesses featured on Bar Rescue are under no obligation to follow any of the rescue protocols or keep any of the changes. All renovations and improvements are paid for by sponsors, with no cost to the businesses. Sports Bar, Events, Arcade, Killer Bar Food, DJs, Dancing, Beer Pong, Clubby, multi-room sports bar with flat-screen TVs, ping pong, darts, simple pub grub. It is commonly believed that Taffer takes a percentage of the businesses he rescues however, this is totally untrue. It stars Jon Taffer (a long-time food and beverage industry consultant specializing in nightclubs and pubs), who offers his professional expertise, access to service industry experts, and renovations and equipment to desperately failing bars in order to save them from closing. Time Out West Sports Pub, Hanover Park, Illinois. ![]() “First Bunny” Old Town (South of North Ave.Bar Rescue is an American reality TV series that premiered on Paramount Network (formerly Spike) on July 17, 2011.Joe’s Bebop Cafe & Jazz Emporium Gold Coast (Near North) Time Out West Sports Pub, Hanover Park, Illinois. Time Out West Sports Pub, Hanover Park, Illinois.Terrace at Conrad Hotel Streeterville (Near North).in 2 reviews After all was said and done - 2 apps, 3 22oz. Whether it’s the Bears, Cubs, Sox, Bulls, Blackhawks or an alma mater, there are numerous games to watch every. ![]()
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Activate draftsight9/17/2023 ![]() This is completely incompatible with the premise of working on my office computer OR my home laptop. (*) All other CAD packages seem to require you run "server" software to share the license on other hardware and uselessly the computers must all share the same network. I can probably rationalize that over $180 for, say, NanoCad with it's horrid licensing limits(*). "Summer sale", whatever the hell that means, is $800 for a 3 year term. ![]() Now I'm faced with contemplating a subscription to ACAD LT. Geez what a difference! I haven't used Autocad in about 8 years and I was instantly back on track getting the job done in about a third of the time and with NO frustration. In a fit of frustration with some of Draftsight's own idiocy I downloaded the trial form of ACAD Lite. Kcress - RE: Draftsight 2019 - no longer Free itsmoked (Electrical) 21 Jul 19 03:30 What the hell's wrong with them? How hard is it to keep track of how many copies of a license are running on the planet? NanoCAD does offer floating licences except they demand the floaters be on the same network. So that would mean I'd have to buy 2 copies even though only one would ever be running at a time. I work on drawings at home and at the office and they're allowing only one CPU period. I'd probably go with DraftSight except their licensing sucks for me. (Free for hobbyists or companies doing less than x$ business.) It's also twice the price of DraftSight.Īs for DraftSight ransoming our drawings, is that really true? Can't we store them on our hardware and access them with any DFX or DWG tool? This is not like Fusion360 where you really are ransomed except they have a really generous licencing agreement. I hope nanoCAD doesn't pull the same trick on us. Kcress - RE: Draftsight 2019 - no longer Free SBaugh (Mechanical) I'm glad to hear there are some alternatives. It would appear and in the time it took to read the file name it would vaporize it and my antiV would pop up a window to inform me of a 'save'. ![]() Hilariously my anti virus program found and nixed the keycracker every time it opened. I thought about using a cracked version to keep the files on MY computer instead of their cloud. So today the same thing 'you must activate (again!)' but with that nasty in- red you shall bend over after December. Really aggravating, especially since the activation process was broken about half the time. I've always cursed the Dassault idiots because on two computers at least one would be whining about needing to be "activated" every rare time I opened it. I use DraftSight about 10 times a year to cobble up a cnc router part or a field wiring diagram. ![]()
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Halo 2 online gameplay famous young kid9/17/2023 ![]() ![]() Blue and I still remember meeting Burnie for the first time and how Microsoft's first instinct was to shut them down or charge huge licenses but Pete and myself (and others) fought for the marketing and promotional merits of their work and a phenomenon was born. We got called out for that even though it wasn't really a 'bull shot.' But damn they looked great. Since it was impossible to really coordinate and get an exact moment we had to use fixed cameras, stage each player as a separate screenshot and then composite it all together. We didn't have saved films so we had to use the console command to set 'gamespeed 0' and try to freeze it at the exact right time. I look at all the screenshots we released for Halo 2 and pretty much remember taking every single one. Zanzibar was amazing fun and the shenanigans of Warthogs getting caught up in the turbine wheel never ceased to entertain. We did so many demos over the span of that E3 and beyond. I can still nearly recite the entire thing by heart. On Twitter I posted a photo of the original Halo 2 Multiplayer demo script I found in a box of keepsakes. I was enamored with meeting Jen Taylor in person and hanging out with David Scully (Sgt Johnson) who had me in tears with laughter all night (he was in character ALL NIGHT). Jason even made a surprise appearance and signed autographs and mingled (super rare even back then!). I'll never forget our big after hours FanFest we did in the Xbox booth at E3 when we got free run of the entire floor and Jaime Griesemer went completely off script in the demo theater and our fans loved every second of it. This continued for days and weeks, I still have no idea how he did that. The test manager had a fridge at his desk and would start the day around 7AM drinking beers around the clock and be full into hard alcohol by early afternoon. ![]() At the time I couldn't believe that the team would actually get that amount of work done in the crazy short amount of time left until launch. I remember a meeting where Jason Jones had white boards of all the game's missions and basically explained how nearly half the game was being scrapped and would have to be re-done. I remember the "Space Pickle" announce trailer and how amazing it looked and then going to a team meeting and learning that the entire underlying tech had to be ripped out because the lighting system wasn't going to be practical. ![]() I remember frantically working to build and deliver a first-of-it's-kind console/web stats experience (we looked at what Epic had been doing on PC as a what we wanted to strive for). I joined Bungie two years before we shipped Halo 2 and man was it a whirlwind. In threads with a vague title and Rumor/Leak flair detailed outline on acceptable titlesĪhhh so many memories both internally with Bungie and externally with the community.Lore may be freely discussed three months past release. New official lore and datamined/leaked game content are spoilers. Live Now! □║24 Hour Multiplayer Madness!. The only !drops here involve my dance mo. $$1v1's + $$75 FFA 35th BIRTHDAY BASH pt2 R/Halo Discord + LFG | Infinite Season 4 | 343 Plz | Game FAQs ![]()
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Das boot series episodes9/17/2023 ![]() It's a shame that Cassandra’s languid crooning at Minton’s jazz club doesn’t bear much resemblance to the bebop revolution that was erupting there at the time. Less compelling is the storyline about U-boat captain Klaus Hoffman (Rick Okon), washed up in New York after being cast adrift on the Atlantic, and now involved in a love affair with Harlem jazz singer Cassandra Lloyd (Rochelle Neil). The American angle, featuring US Nazi sympathisers and business tycoon Jack Greenwood’s treasonous relationship with the Third Reich, could easily evolve into a series of its own. ![]() One problem looming increasingly large for the Das Boot team is how to keep the submarine warfare strand connected to the increasingly diverse activities going on elsewhere. Nazi butcher suddenly discovers he has a heart? There will not be laughter in Berlin. As for the bold plan by French resisters to free prisoners being shipped off to a concentration camp by staging a fake railway breakdown, the gruesome torture of police chief Pierre Duval (Thierry Frémont) gave the Nazis the information they needed.īut perhaps there was a premonition of future events when Margot pleaded with Gestapo man Forster (Tom Wlaschiha) – now promoted to a top job supervising the Final Solution – to show “pitié pour les enfants”, and a momentary flash of anguish seemed to cross his face. In occupied France, Margot (Fleur Geffrier) had been battling desperately to save a Jewish family fleeing the Germans by guiding them to Spain, only to find herself betrayed by the Catholic priest she’d been forced to trust. Many have been found wanting, but others have discovered something fine within themselves.Īs it sped towards a conclusion – although not one so conclusive that it didn’t leave plenty of potential for series 3 – the horror of total war continued to exert crushing force. ![]() ![]() You could argue that it sometimes overreached by stretching the scope of the narrative to breaking point, but at its core it’s a study of human values under impossible pressure. ![]()
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![]() ![]() You can view more photos of our Germantown office below. ![]() Saddle Creek Orthodontics is also surrounded by dozens of shopping options in Germantown at the nearby Shops of Saddle Creek including the Apple store, Anthropologie, and J.Crew, while Saddle Creek Orthodontics Collierville is close to several schools including Houston Middle School and High School, Bailey Station Elementary School, Schilling Farms Middle School, Collierville High School, and Crosswind Elementary School. That means great orthodontic care is only a few minutes from your home, work, or school. including Altard State, Anthropologie, Apple Store, Athleta. It is located in the eastern Memphis, Tennessee suburb of Germantown. Saddle Creek Orthodontics is less than 10 minutes from where you live in East Memphis, Cordova, and Collierville. Saddle Creek is the first shopping center in the nation developed as a lifestyle center. phone: (901) 309-6000 distance from Memphis, TN: 7.2 miles iPod Store: yes iPad Store: no. Our Collierville office is located near the intersection of Poplar and Houston Levee, directly in front of Life Time Fitness. Apple Store Saddle Creek 7615 W Farmington Blvd Germantown, TN 38138. Our Collierville location was built from scractch and recently opened in May 2016.Ĭlean: At Saddle Creek Orthodontics, we utilize state of the art digital records hosted on Mac computers, above-standard sterilization methods, and comfortable treatment chairs.Ĭonveniently located: Our Germantown office is positioned right in the heart of Germantown, in between Poplar and Poplar Pike. The waiting room features complimentary WiFi, bottled water, soft drinks, and dozens of varieties of Keurig fresh-brewed coffee. Fabletics at the Shops of Saddle Creek Location: 7615 West Farmington, Suite 24, Germantown Hours: 10 a.m.-8 p.m. Modern: Our Germantown orthodontic clinic was completely renovated both inside and out during 2013. At Saddle Creek Orthodontics, we believe an orthodontic office should be modern, clean, and conveniently located. ![]()
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Traffic cone color crossword9/17/2023 ![]() ![]() Purplish fruit used in smoothies crossword clue ![]() first two and last three letters) crossword clue Kerri Walsh Jennings' volleyball teammate (. football club nickname whose first word drops -chester crossword clue Home of Hawaii's Hana Highway crossword clue Make an offer, at a silent auction crossword clue Green sauce used on fusilli crossword clue _ Johnson, American professional golfer who won the 2016 U.S. Washday item that may be used indoors or outdoors crossword clue Online platform for raising money crossword clue Political campaign made up of a series of short appearances crossword clue TV network with many home-improvement shows crossword clue Wax-wrapped cheese from Holland crossword clue With 5-Across, first woman of color on a national major-party ticketĭid you get the correct answer for your Color of a traffic cone crossword clue? Then check out this Universal Crossword Jother crossword clue. With 58-Across, what's represented by this puzzle's colored "stripes" Works of art often made from pieces of colored glass _ Avenue (Monopoly property in the same color group as Mediterranean Avenue) _ Cover (independent bookstore chain in Denver, Colorado) BIV (name that helps people remember the rainbow colors) _ Krupp who won the Stanley Cup with Colorado Avalanche _ ring (1970s novelty item that changed color) We think ORANGE is the possible answer on this clue.Ĭrossword clues for Color of a traffic cone Clue This answers first letter of which starts with O and can be found at the end of E. The crossword clue possible answer is available in 6 letters. ![]() This crossword clue Color of a traffic cone was discovered last seen in the Jat the Universal Crossword. ![]()
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Gimp move selection one direction only9/17/2023 ![]()
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